Ah, sorry I misunderstood the root of the problem you were asking about. I think you are trying to apply the wrong statute. Section 3121 was put in place for the primary purpose of assuring lenders that a residential property they are financing will remain accessible (i.e. not become functionally land locked due to lack of maintenance.)
Your question has more to do with someone who has other access, but who may occasionally use the private road as additional access. You said, "if there is no road association, it is all we have." I don't believe section 3121 will help you much in this situation. It starts off with, "If more than one property shares a common benefit from a private road..." I think the resident you are referring to would argue that a person whose primary access is via a different road does not share a common benefit, since, as you say, they do not routinely use the road to drive to their house.
But if you have no road association, it may well be in your interest to look into forming a statutory road association under 23 MRS sections 3101-3104. Section 3101 says it includes "the owners of all the parcels benefited by the private road."
It does say, "When 4 or more parcels of land are benefited by a private road, private way or bridge as an easement or by fee ownership of the private road, private way or bridge..." But I think that has more to do with establishing the existence of the road as a private road, than dictating who will be members of the association. It then goes on to say that notice of the initial meeting must be sent "to the owners of all the parcels benefited by the private road, private way or bridge ..." I would argue that a statutory road association therefore includes everyone who benefits from the road, regardless of whether it is their primary access to their residence, and regardless of whether they have any easement or fee ownership of the road. In the case you describe, it certainly sounds like this property is "benefited by" the road.
There have been disputes before over whether a person must pay dues to an association if their property abuts the private road but they do not use that road for access to their property. The usual conclusion is that while the association may decide it's "fair and equitable" to charge them at a lower rate, they do need to pay something because the road does provide access to their property, which they could decide to use at any time. It also provides emergency access in case, for example, there is a brush fire on the back side of their property.
If you were to form a statutory road association, you would then be able to use the "Notice of Claim" process if necessary to collect a fair assessment for this person's use of the road. You might, however, decide that "fair and equitable" would required charging them a lesser assessment than those who use the road daily as their primary access.
One final thought - if I understand you correctly, you were hoping to use section 3121 because you have no road association. Section 3121 essentially creates a road association, but aside from a passing mention of "after reasonable due process and notice," it gives no guidelines for how that is to be done, and the only enforcement power is through taking the offender to court. So the only reason I can see for trying to use section 3121 instead of 3101 in a situation like yours would be if you do not have section 3101's required four landowners, three of whom agree to call the initial meeting. If you are having difficulty getting those three original signers, I would strongly recommend you attend the MARA Conference on Oct 4th, where you can network with others to learn how they got started.